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政策法规 现行有效美国危险品合规

§ 173.127 Class 5, Division 5.1—Definition and assignment of packing groups.

效力法规类型发布日期生效日期发文机构
现行有效部门规章2026-08-072026-09-08Code of Federal Regulations (CFR) - Transportation (Title 49)
发布08-07
生效09-08
摘要总结AI 辅助解读
该法规(49 CFR § 173.127)定义了美国运输部对第5.1类氧化剂的危险品分类标准及包装组别分配规则。核心内容在于依据《联合国试验和标准手册》中的特定测试方法(如固体O.1/O.3测试,液体压力上升时间测试),将物质划分为I、II、III级包装组或排除出危险品范畴。对于从事涉美出口或进口业务的货代、外贸及物流服务商而言,准确判定氧化剂的包装组别直接决定了合规的UN编号、包装要求及申报义务,是危险品操作的基础依据。
官方原文
外文原文 · 可AI翻译 · 可溯源
  • (a) Definition. For the purpose of this subchapter, oxidizer (Division 5.1) means a material that may, generally by yielding oxygen, cause or enhance the combustion of other materials.

- (1) A solid material, except for solid ammonium nitrate based fertilizer (see paragraph (a)(3) of this section), is classed as a Division 5.1 material if, when tested in accordance with the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter):

  • (i) If test O.1 is used (UN Manual of Tests and Criteria, sub-section 34.4.1), the mean burning time is less than or equal to the burning time of a 3:7 potassium bromate/cellulose mixture; or

- (ii) If test O.3 is used (UN Manual of Tests and Criteria, sub-section 34.4.3), the mean burning rate is greater than or equal to the burning rate of a 1:2 calcium peroxide/cellulose mixture.

- (2) A liquid material is classed as a Division 5.1 material if, when tested in accordance with the UN Manual of Tests and Criteria, it spontaneously ignites or its mean time for a pressure rise from 690 kPa to 2070 kPa gauge is less then the time of a 1:1 nitric acid (65 percent)/cellulose mixture.

- (3) Solid ammonium nitrate-based fertilizers must be classified in accordance with the procedure as set out in the UN Manual of Tests and Criteria, Part III, Section 39.

  • (b) Assignment of packing groups. (1) The packing group of a Division 5.1 material which is a solid shall be assigned using the following criteria:
  • (i) Packing Group I, for any material which, in either concentration tested:
  • (A) If test O.1 is used (UN Manual of Tests and Criteria, sub-section 34.4.1), the mean burning time is less than the mean burning time of a 3:2 potassium bromate/cellulose mixture; or
  • (B) If test O.3 is used (UN Manual of Tests and Criteria, sub-section 34.4.3), the mean burning rate is greater than the mean burning rate of a 3:1 calcium peroxide/cellulose mixture.

- (ii) Packing Group II, for any material which, in either concentration tested:

  • (A) If test O.1 is used (UN Manual of Tests and Criteria, sub-section 34.4.1), the mean burning time is less than the mean burning time of a 2:3 potassium bromate/cellulose mixture and the criteria for Packing Group I are not met; or
  • (B) If test O.3 is used (UN Manual of Tests and Criteria, sub-section 34.4.3), the mean burning rate is greater than the mean burning rate of a 1:1 calcium peroxide/cellulose mixture and the criteria for Packing Group I are not met.

- (iii) Packing Group III for any material which, in either concentration tested:

  • (A) If test O.1 is used (UN Manual of Tests and Criteria, sub-section 34.4.1), the mean burning time is less than the mean burning time of a 3:7 potassium bromate/cellulose mixture and the criteria for Packing Groups I and II are not met; or
  • (B) If test O.3 is used (UN Manual of Tests and Criteria, sub-section 34.4.3), the mean burning rate is greater than the mean burning rate of a 1:2 calcium peroxide/cellulose mixture and the criteria for Packing Groups I and II are not met.

- (iv) The materials is not classified as a Division 5.1 material if, in either concentration tested:

  • (A) If test O.1 is used (UN Manual of Tests and Criteria, sub-section 34.4.1), the sample tested does not ignite and exhibit burn, or exhibits a mean burning time of greater than or equal to the mean burning time of a 3:7 potassium bromate/cellulose mixture.
  • (B) If test O.3 is used (UN Manual of Tests and Criteria, sub-section 34.4.3), the sample tested does not ignite and exhibit burn, or exhibits a mean burning rate less than or equal to the mean burning rate of a 1:2 calcium peroxide/cellulose mixture.

- (2) The packing group of a Division 5.1 material which is a liquid shall be assigned using the following criteria:

  • (i) Packing Group I for:
  • (A) Any material which spontaneously ignites when mixed with cellulose in a 1:1 ratio; or
  • (B) Any material which exhibits a mean pressure rise time less than the pressure rise time of a 1:1 perchloric acid (50 percent)/cellulose mixture.

- (ii) Packing Group II, any material which exhibits a mean pressure rise time less than or equal to the pressure rise time of a 1:1 aqueous sodium chlorate solution (40 percent)/cellulose mixture and the criteria for Packing Group I are not met.

- (iii) Packing Group III, any material which exhibits a mean pressure rise time less than or equal to the pressure rise time of a 1:1 nitric acid (65 percent)/cellulose mixture and the criteria for Packing Group I and II are not met.

[Amdt. 173-261, 62 FR 24732, May 6, 1997, as amended at 68 FR 75744, Dec. 31, 2003; 80 FR 1156, Jan. 8, 2015; 80 FR 72924, Nov. 23, 2015; 85 FR 27880, May 11, 2020]
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